Palladium

Palladium

This grayish-white, precious metal is valued because of its rarity, malleability, stability under hot conditions, and ability to absorb a considerable amount of hydrogen at room temperature.
  • Appearance : A shin, lustrous, silvery-white metal

  • Symbol : Pd

  • Atomic number : 46

  • Atomic weight : 106.42

  • Found in : Brazil, South Africa, Montana, United States, Canada, and Russia.

  • Uses : catalytic converters for cars, ceramic capacitors, jewellery and some dental fillings and crowns.


Discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.


A shiny, silvery-white metal that resists corrosion.


Palladium has no known biological role. It is non-toxic.


Most palladium is used in catalytic converters for cars. It is also used in jewellery and some dental fillings and crowns. White gold is an alloy of gold that has been decolourised by alloying with another metal, sometimes palladium.


It is used in the electronics industry in ceramic capacitors, found in laptop computers and mobile phones. These consist of layers of palladium sandwiched between layers of ceramic.


Finely divided palladium is a good catalyst and is used for hydrogenation and dehydrogenation reactions. Hydrogen easily diffuses through heated palladium and this provides a way of separating and purifying the gas.


As early as 1700, miners in Brazil were aware of a metal they called ouro podre, ‘worthless gold,’ which is a native alloy of palladium and gold. However, it was not from this that palladium was first extracted, but from platinum, and this was achieved in 1803 by William Wollaston. He noted that when he dissolved ordinary platinum in aqua regia (nitric acid + hydrochloric acid) not all of it went into solution.


It left a residue from which he eventually extracted palladium. He did not announce his discovery but put the new metal on sale as a ‘new silver’. Richard Chenevix purchased some, investigated it, and declared it to be an alloy of mercury and platinum. In February 1805 Wollaston revealed himself as its discoverer and gave a full and convincing account of the metal and its properties.


At about $2,500 (£1,922) an ounce of palladium is more expensive than gold, and the pressures forcing its price up are unlikely to ease anytime soon.


The majority of the world’s palladium comes from Russia and South Africa. Most of it is extracted as a byproduct in the mining of other metals, usually platinum and nickel.